Deprotection of Acetals and Silyl Ethers Using Some. PI.-Acceptors.

K Tanemura, T Suzuki, T Horaguchi

文献索引：Tanemura, Kiyoshi; Suzuki, Tsuneo; Horaguchi, Takaaki Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 1 p. 290 - 292

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被引用次数: 38

摘要

Hydrolysis of dodecanal dimethyl acetal and dodecyl silyl ethers in MeCN–H 2 O was examined using a catalytic amount of π-acceptors such as 2, 3-dichloro-5, 6-dicyano-p- benzoquinone (DDQ), tetracyanoethylene (TCNE), 7, 7, 8, 8-tetracyanoquinodimethane (TCNQ), 2, 3, 5, 6-tetrafluoro-7, 7, 8, 8-tetracyanoquinodimethane (TCNQF 4), and chloranil (CA). Cleavage of dodecyl triethylsilyl ether with TCNQ and CA was caused by room light. ...