The Journal of Organic Chemistry

Catalytic replacement of unactivated alkane carbon-hydrogen bonds with carbon-X bonds (X= nitrogen, oxygen, chlorine, bromine, or iodine). Coupling of …

CL Hill, JA Smegal, TJ Henly

文献索引：Hill, Craig L.; Smegal, John A.; Henly, Timothy J. Journal of Organic Chemistry, 1983 , vol. 48, # 19 p. 3277 - 3281

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被引用次数: 53

摘要

A simple system has been devised to facilitate the first processes for the catalytic replacement of unactivated alkane CH bonds with CX bonds, X= nitrogen and iodine. The system also enables alkane CH bonds to be replaced by CX bonds, X= chlorine, bromine, and oxygen. The system is composed of two liquid phases and the oxidant iodosylbenzene (iodosobenzene). The alkane substrate, the MnmWPX catalyst, and the organic solvent ( ...