Organosilicon compounds. L. Pyrolysis of phenyldimethylsilane

F Mareš, V Chvalovský

文献索引：Mares,M.; Chvalovsky,V. Collection of Czechoslovak Chemical Communications, 1967 , vol. 32, # 1 p. 382 - 397

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被引用次数: 9

摘要

The predominant products of pyrolysis of phenyldimethylsilane, studied in a through-Aow reactor, have proved to be diphenyldimethylsilane, 9, 9-dimethyl-9-silafluorene, and polymers: benzene and toluene are formed to a small extent. For comparison we have studied the kinetics of pyrolysis of p-tolyldimethylsilane, giving rise to the analogous p- methylsubstituted products, and of diphenyldimethylsilane, which produces benzene, ...