Journal of the American Chemical Society

Imine-Bridged Planar Poly (p-phenylene) Derivatives for Maximization of Extended. pi.-Conjugation. The Common Intermediate Approach

JJS Lamba, JM Tour

文献索引：Lamba, Jaydeep J. S.; Tour, James M. Journal of the American Chemical Society, 1994 , vol. 116, # 26 p. 11723 - 11736

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被引用次数: 136

摘要

Abstract: Described are two approaches to planar conjugated poly@-phenylene)(PPP) derivatives. The first approach, involving lactam bridges, was unsuccessful due to the insolubility of the 6 (5H)-phenanthridinonyl moieties. The second approach, which utilized imine bridges, worked excellently since the compounds were generally soluble and the bridge formations were highly efficient. The main PPP backbone was synthesized via Pd ( ...