Organometallics

Synthesis and Reactivity of [(C2F5) 2MeP] 2Pt (Me) X (X= Me, O2CCF3, OTf, OSO2F): A Reactivity Comparison with Chelate Acceptor Analogues

JL Butikofer, JM Hoerter, RG Peters…

文献索引：Butikofer, Jeffrey L.; Hoerter, Justin M.; Peters, R. Gregory; Roddick, Dean M. Organometallics, 2004 , vol. 23, # 3 p. 400 - 408

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被引用次数: 43

摘要

The syntheses of platinum complexes with the fluoroalkyl acceptor phosphine (C2F5) 2P (Me)(dfmp), cis-(dfmp) 2Pt (Me) 2, and trans-(dfmp) 2Pt (Me)(X)(X= O2CCF3, OTf, OSO2F) are presented. The thermal, chemical, and protolytic stabilities of these systems are described and contrasted with the chelating fluoroalkylphosphine analogue (C2F5) 2PCH2CH2P (C2F5) 2 (dfepe).