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举例 :可输入Filippa Pettersson 或者 Cancer Res. 75(6) , 1102-12, (2015) 或者10.1002/anie.201600521

New and effective routes to fluoro analogs of aliphatic and aromatic amino acids

…, K Nakahashi, T Fuchikami, M Fujita

文献索引：Ojima, Iwao; Kato, Koji; Nakahashi, Kazuaki; Fuchikami, Takamasa; Fujita, Makoto Journal of Organic Chemistry, 1989 , vol. 54, # 19 p. 4511 - 4522

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被引用次数: 108

摘要

Trifluorovaline (1) and trifluoronorvaline (2) are synthesized through amidocarbonylation of 2-(trifluoromethy1) propanal (2-TFMPA) and 3-(trifluoromethyl) propanal (3-TFMPA), respectively, followed by hydrolysis. Trifluoroleucine (5) and trifluoronorleucine (6) are ...

2-phenyl-4-(4,4,4-trifluorobutylidene)-5-oxazolone结构式

2-phenyl-4-(4,4...

~69%

6,6,6-三氟正亮氨酸结构式

6,6,6-三氟正亮氨酸

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N-benzoyl-6,6,6-trifluoronorleucine ethyl ester结构式

N-benzoyl-6,6,6...

~69%

6,6,6-三氟正亮氨酸结构式

6,6,6-三氟正亮氨酸

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2-phenyl-4-[2-(trifluoromethyl)propylidene]-5-oxazolone结构式

2-phenyl-4-[2-(...

~%

5,5,5-三氟-DL-亮氨酸结构式

5,5,5-三氟-DL-亮氨酸

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未登录结构式

~%

5,5,5-三氟-DL-亮氨酸结构式

5,5,5-三氟-DL-亮氨酸

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N-benzoyl-5,5,5-trifluoroleucine methyl ester结构式

N-benzoyl-5,5,5...

~%

5,5,5-三氟-DL-亮氨酸结构式

5,5,5-三氟-DL-亮氨酸

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2-phenyl-4-[2-(trifluoromethyl)propylidene]-5-oxazolone结构式

2-phenyl-4-[2-(...

~%

5,5,5-三氟-DL-亮氨酸结构式

5,5,5-三氟-DL-亮氨酸

5,5,5-三氟-DL-亮氨酸结构式

5,5,5-三氟-DL-亮氨酸

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4,5,6,7-tetrafluoro-3-methyl-1H-indole结构式

4,5,6,7-tetrafl...

乙酸酐结构式

~93%

1-(4,5,6,7-tetrafluoro-3-methylindol-1-yl)ethanone结构式

1-(4,5,6,7-tetr...

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2-(pentafluorophenyl)propanal结构式

2-(pentafluorop...

~%

1-(4,5,6,7-tetrafluoro-3-methylindol-1-yl)ethanone结构式

1-(4,5,6,7-tetr...

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未登录结构式

~%

1-(4,5,6,7-tetrafluoro-3-methylindol-1-yl)ethanone结构式

1-(4,5,6,7-tetr...

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N-(2-(perfluorophenyl)propylidene)prop-2-en-1-amine结构式

N-(2-(perfluoro...

~%

1-(4,5,6,7-tetrafluoro-3-methylindol-1-yl)ethanone结构式

1-(4,5,6,7-tetr...

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4,5,6,7-tetrafluoro-3-methyl-1H-indole结构式

4,5,6,7-tetrafl...

对甲苯磺酰氯(PTSC)结构式

对甲苯磺酰氯(PTSC)

~91%

4,5,6,7-tetrafluoro-3-methyl-1-(4-methylphenyl)sulfonylindole结构式

4,5,6,7-tetrafl...

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2-(pentafluorophenyl)propanal结构式

2-(pentafluorop...

~%

4,5,6,7-tetrafluoro-3-methyl-1-(4-methylphenyl)sulfonylindole结构式

4,5,6,7-tetrafl...

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未登录结构式

~%

4,5,6,7-tetrafluoro-3-methyl-1-(4-methylphenyl)sulfonylindole结构式

4,5,6,7-tetrafl...

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N-(2-(perfluorophenyl)propylidene)prop-2-en-1-amine结构式

N-(2-(perfluoro...

~%

4,5,6,7-tetrafluoro-3-methyl-1-(4-methylphenyl)sulfonylindole结构式

4,5,6,7-tetrafl...

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氰化钾结构式

3-[(N-methylpiperidiniumyl)methyl]-4,5,6,7-tetrafluoroindolyl methyl sulfate结构式

3-[(N-methylpip...

~95%

2-(4,5,6,7-tetrafluoro-1H-indol-3-yl)acetonitrile结构式

2-(4,5,6,7-tetr...

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4,5,6,7-tetrafluoro-3-(piperidin-1-ylmethyl)-1H-indole结构式

4,5,6,7-tetrafl...

~%

2-(4,5,6,7-tetrafluoro-1H-indol-3-yl)acetonitrile结构式

2-(4,5,6,7-tetr...

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4,5,6,7-四氟吲哚-3-甲醛结构式

4,5,6,7-四氟吲哚-3-甲醛

硝基甲烷结构式

~90%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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4,5,6,7-tetrafluoro-3-methyl-1H-indole结构式

4,5,6,7-tetrafl...

~%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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2-(pentafluorophenyl)propanal结构式

2-(pentafluorop...

~%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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未登录结构式

~%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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1-(4,5,6,7-tetrafluoro-3-methylindol-1-yl)ethanone结构式

1-(4,5,6,7-tetr...

~%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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Methanone, phenyl(4,5,6,7-tetrafluoro-3-methyl-1H-indol-1-yl)结构式

Methanone, phen...

~%

4,5,6,7-tetrafluoro-3-(2-nitroethenyl)-1H-indole结构式

4,5,6,7-tetrafl...

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未登录结构式

~%

4,5,6,7-tetrafluoro-3-methyl-1H-indole结构式

4,5,6,7-tetrafl...

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2-acetamido-5,5,5-trifluoropentanoic acid结构式

2-acetamido-5,5...

~79%

Norvaline, 5,5,5-trifluoro结构式

Norvaline, 5,5,...

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2-(4,5,6,7-tetrafluoro-1H-indol-3-yl)acetonitrile结构式

2-(4,5,6,7-tetr...

~96%

(4,5,6,7-TETRAFLUORO-1H-INDOL-3-YL)ACETICACID结构式

(4,5,6,7-TETRAF...

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4,5,6,7-tetrafluoro-3-(piperidin-1-ylmethyl)-1H-indole结构式

4,5,6,7-tetrafl...

~%

(4,5,6,7-TETRAFLUORO-1H-INDOL-3-YL)ACETICACID结构式

(4,5,6,7-TETRAF...

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3-[(N-methylpiperidiniumyl)methyl]-4,5,6,7-tetrafluoroindolyl methyl sulfate结构式

3-[(N-methylpip...

~%

(4,5,6,7-TETRAFLUORO-1H-INDOL-3-YL)ACETICACID结构式

(4,5,6,7-TETRAF...

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2-phenyl-4-(4,4,4-trifluorobutylidene)-5-oxazolone结构式

2-phenyl-4-(4,4...

~%

(2S)-2-amino-6,6,6-trifluorohexanoic acid结构式

(2S)-2-amino-6,...

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ethyl (Z)-2-benzamido-5-(trifluoromethyl)-2-pentenoate结构式

ethyl (Z)-2-ben...

~%

(2S)-2-amino-6,6,6-trifluorohexanoic acid结构式

(2S)-2-amino-6,...

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6,6,6-三氟正亮氨酸结构式

6,6,6-三氟正亮氨酸

~%

(2S)-2-amino-6,6,6-trifluorohexanoic acid结构式

(2S)-2-amino-6,...

查看详情

N-benzoyl-6,6,6-trifluoronorleucine ethyl ester结构式

N-benzoyl-6,6,6...

~%

(2S)-2-amino-6,6,6-trifluorohexanoic acid结构式

(2S)-2-amino-6,...

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Fluorine containing amino acids and their derivatives. 7. Sy...

[Tetrahedron, , vol. 44, # 17 p. 5375 - 5387]

New and effective routes to fluoro analogs of aliphatic and ...

[Journal of Organic Chemistry, , vol. 54, # 19 p. 4511 - 4522]