Conjugation in the Naphthalene Series. II. 1 Solvolysis of x-Methoxy-y-bromomethylnaphthalenes

KC Schreiber, RG Byers

文献索引：Schreiber,K.C.; Byers,R.G. Journal of the American Chemical Society, 1962 , vol. 84, p. 859 - 862

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被引用次数: 10

摘要

The solvolyses in acetic acid and 80% aqueous acetone of 4-, 5-, 6-and 7-methoxy-l- bromomethylnaphthalene, and 6-and 8-methoxy-2-bromomethylnaphthalenes are reported at various temperatures. The data indicate that there is little resonance stabilization of the carbonium ion by the methoxy group in the intermediates from 5-methoxy-1-bromomethyl or the 8-methoxy-2-bromomethyl compounds. h small effect is observed in the case of the 7- ...