Reduction of methylated anthraquinones to methylated anthracenes with aluminium tri (cyclohexyl oxide)

NG Gaylord, V Štěpán

文献索引：Gaylord,N.G.; Stepan,V. Collection of Czechoslovak Chemical Communications, 1974 , vol. 39, p. 1700 - 1710

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被引用次数: 7

摘要

The effect of reaction conditions has been examined in the aluminium tri (cyclohexyloxide) reductions of 1, 3-and 2, 3-dimethyl-9, 10-anthraquinone to 1, 3-and 2, 3- dimethylanthracene. With the use of the same reagent, the following compounds have been also prepared; 1-and 2-methyl-, 1, 2-, 1, 4-, 2, 6-, and 2, 7-dimethyl-, 2, 3, 6-trimethyl-, and 2, 3, 6, 7-tetramethylanthracene. A mechanism of the aluminium tri (cyclohexy {oxide) ...