Phosphorus and Sulfur and the Related Elements

REACTIONS IN THE CHLOROSILANE-SILANOL-SILOXANE SYSTEM

K Rühlmann

文献索引：Ruehlmann, K. Phosphorus and Sulfur and the Related Elements, 1986 , vol. 27, p. 139 - 152

全文：HTML全文

被引用次数: 2

摘要

Abstract We obtained the first σ∗-values and Es-values for siloxy groups by spectroscopic and kinetic methods. Detailed mechanistic investigations are performed on the hydrolysis of chlorosiloxanes, the cleavage of Si [sbnd] O [sbnd] Si bonds by HCl, and the substituent exchange reaction between silanols and chlorosilanes.