Tetrahedron letters

New tridentate cyclometalated platinum (II) and palladium (II) complexes of N, 2-diphenyl-8-quinolinamine: syntheses, crystal structures, and photophysical properties

L Mao, T Moriuchi, H Sakurai, H Fujii, T Hirao

文献索引：Mao, Lisheng; Moriuchi, Toshiyuki; Sakurai, Hidehiro; Fujii, Hiroyuki; Hirao, Toshikazu Tetrahedron Letters, 2005 , vol. 46, # 48 p. 8419 - 8422

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被引用次数: 23

摘要

A new tridentate cyclometalated platinum (II) complex derived from N, 2-diphenyl-8- quinolinamine, which consists of two crystallographic independent molecules with two intermolecular N–H–Cl–Pt hydrogen bonds forming a dimer, exhibited a low-energy luminescence at ca. 740nm in a 1× 10− 3M dichloromethane solution and a strong emission centered at 670nm in a solid state, but the analogous palladium (II) complex was ...