1, 6-Diene Complexes of Palladium (0) and Platinum (0): Highly reactive sources for the naked metals and [L-M0] Fragments

…, G Cestaric, KJ Haack, K Seevogel…

文献索引：Krause, Jochen; Cestaric, Guenter; Haack, Karl-Josef; Seevogel, Klaus; Storm, Werner; Poerschke, Klaus-Richard Journal of the American Chemical Society, 1999 , vol. 121, # 42 p. 9807 - 9823

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被引用次数: 92

摘要

The complexes (cod) MCl2 (M= Pd, Pt; cod= cis, cis-1, 5-cyclooctadiene) react with Li2 (cot)(cot= cyclooctatetraene) in a 1, 6-diene/diethyl ether mixture (1, 6-diene= hepta-1, 6- diene, diallyl ether, dvds (1, 3-divinyl-1, 1, 3, 3-tetramethyldisiloxane)) to afford the isolated homoleptic dinuclear Pd0 and Pt0 compounds Pd2 (C7H12) 3 (1), Pd2 (C6H10O) 3⊙ C6H10O (2'; 2: Pd2 (C6H10O) 3), Pd2 (dvds) 3 (3), and Pt2 (C7H12) 3 (4). When 1-4 are ...