Selectivity of catalytic systems RhCl3· Polycation in hydroformylation of hex-1-ene under conditions of biphase catalysis

NV Kolesnichenko, MV Sharikova…

文献索引：Kolesnichenko; Sharikova; Murzabekova; Markova; Slivinskii Russian Chemical Bulletin, 1996 , vol. 45, # 8 p. 1866 - 1869

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摘要

Abstract Approaches to increasing the selectivity of water-soluble catalytic systems based on RhCl 3 and polycation in hydroformylation of hex-1-ene were studied. The introduction of a long-chain alkyl radical into the polycation or the use of a higher fatty acid anion results in an increase in the selectivity of the catalytic system at pH> 7 with respect to n-aldehyde to 60%. This effect is presumably associated with the suppression of isomerization processes due ...