Cross Coupling between sp3-Carbon and sp3-Carbon Using a Diborylmethane Derivative at Room Temperature

…, T Ohkubo, T Ishioka, T Shibata

文献索引：Endo, Kohei; Ohkubo, Takahiro; Ishioka, Takafumi; Shibata, Takanori Journal of Organic Chemistry, 2012 , vol. 77, # 10 p. 4826 - 4831

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被引用次数: 39

摘要

A novel example of the Suzuki–Miyaura cross-coupling reaction between sp3-carbon and sp3-carbon is described. The reaction of a diborylmethane derivative with allyl halides or benzyl halides proceeded efficiently in the presence of appropriate Pd-catalysts at room temperature. The present approaches provide functionalized homoallylboronates and alkylboronates with excellent regio-and chemoselectivities.