The Journal of Organic Chemistry

Reaction of 1, 1, 2-trichloro-1, 2, 2-trifluoroethane and other fluorohalocarbons with aluminum halides in the presence and absence of additives. Distinction in …

K Okuhara

文献索引：Okuhara,K. Journal of Organic Chemistry, 1978 , vol. 43, p. 2745 - 2749

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被引用次数: 25

摘要

Results The reaction of CF2ClCFC12 with aluminum chloride showed a marked stirring effect. Thus the isomerization was never complete as far as vigorous stirring6b was continued (for 2, 3, 5, and 7 h) with refluxing. When stirring and external heating were discontinued, refluxing ceased temporarily, but soon the reaction mixture began to reflux again, showing an active occurrence of the isomerization. Thirty minutes after the initial ...