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Tetrahedron

Telomerization reactions in the synthesis of models for some fluorocarbon Polymers

RD Chambers, J Hutchinson, RH Mobbs…

文献索引:Chambers,R.D. et al. Tetrahedron, 1964 , vol. 20, p. 497 - 506

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被引用次数: 37

摘要

Heptafluoro-2-iodopropane, i-C3F7I, is a very efficient chain-transfer agent in telomerization reactions with 1, 1-difluoroethylene and tetrafluoroethylene; other telomerization reactions of CF3I, C2F5I and n-C3F7I with 1, 1-difluoroethylene and of n-C3F7I with tetrafluoroethylene are reported and the relative efficiencies of the iodides as chain-transfer agents are discussed. The telomer iodides have been coverted to useful models for some ...