Journal of the American Chemical Society

Organometallic Derivatives of Carbazole and Quinoline. Amides of 3-Quinoline-carboxylic Acid

H Gilman, SM Spatz

文献索引：Gilman; Spatz Journal of the American Chemical Society, 1941 , vol. 63, p. 1553,1554

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被引用次数: 26

摘要

Two general procedures have been used hitherto for the preparation of organometallic derivatives of carbazole.'One of these involves a direct synthesis from RX compound and magnesium or lithium in poor yields. The other is a metalation reaction which also suffers from the disadvantage of low yields; however, this is compensated by the introduction of the metal in positions not generally accessible by other nuclear substitution reactions. The ...