European Journal of Organic Chemistry

Pd??Catalyzed Threefold Arylation of Baylis–Hillman Bromides and Acetates with Triarylbismuth Reagents

MLN Rao, S Giri

文献索引：Rao, Maddali L. N.; Giri, Somnath European Journal of Organic Chemistry, 2012 , # 24 p. 4580 - 4589

全文：HTML全文

被引用次数: 6

摘要

Abstract Functionalized alkyl 2-benzylacrylates and 2-benzylacrylonitriles were synthesized by means of atom-economic cross-couplings of Baylis–Hillman bromides or acetates with BiAr 3 under palladium-catalyzed conditions. These reactions, involving threefold aryl couplings using BiAr 3 reagents with bromides and acetates, are fast and are completed in 1– 2 h with high product yields.