Journal of the American Chemical Society

Synthesis of 1, 2-and 1, 3-Dicarboxylic Acids via Pd (II)-Catalyzed Carboxylation of Aryl and Vinyl C− H Bonds

R Giri, JQ Yu

文献索引：Giri, Ramesh; Yu, Jin-Quan Journal of the American Chemical Society, 2008 , vol. 130, # 43 p. 14082 - 14083

被引用次数: 235

摘要

A Pd (II)-catalyzed reaction protocol for the direct carboxylation of benzoic and phenylacetic acid derivatives to form dicarboxylic acids has been developed. The reaction conditions are also applicable for the carboxylation of vinyl C− H bonds. The first C− H insertion Pd− aryl complex from carboxylic acids has been characterized by X-ray crystallography.

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14963-97-4

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