Journal of the American Chemical Society

Reductive Cleavages of a Stable Ozonide1

B Witkop, JB Patrick

文献索引：Witkop; Patrick Journal of the American Chemical Society, 1952 , vol. 74, p. 3855,3859

全文：HTML全文

被引用次数: 41

摘要

The stable ozonide IIa from 2-phenylskatole (I) was studied in its spectral and chemical behavior, ThefoIlowingagents were used for reductive cleavage of the ozonide: hydrogen and palladium, lithium aluminum hydride, sodium boron hydride, alkali metal, phenyl-and n- butylmagnesium bromide and methyllithiurn. For the first time a crystalline ozonide and hydroperoxide (VI), both prepared from the same precursor (I), were correlated via their ...