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Studies in organic mass spectrometry. VIII. The electron impact mass spectra of 2, 4??substituted??3??diazo??5??phenylpyrroles

L Ceraulo, P Agozzino, M Ferrugia…

文献索引:Ceraulo, L.; Agozzino, P.; Ferrugia, M.; Plescia, S.; Sprio, V. Journal of Heterocyclic Chemistry, 1990 , vol. 27, # 2 p. 135 - 138

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被引用次数: 1

摘要

Abstract The electron impact mass spectra (75 eV) of the β-diazopyrroles always show the molecular ions and undergo as the main fragmentation process the elimination of nitrogen followed by ring opening reactions leading to benzonitrile either as neutral or charged species. The peaks at 26 amu below the molecular ions, which are a general feature of these spectra, are due to the presence of the corresponding pyrroles which are formed by ...