ZUR KENNTNIS DER ORGANOPHOSPHORVERBINDUNGEN XX: Bifunktionelle Aminophosphane (Et2N) 2P-[CH2] nP (NEt2) 2 und Et2N (R) P-[CH2] nP (R) NEt2

K Diemert, W Kuchen, J Kutter

文献索引：Diemert, Klaus; Kuchen, Wilhelm; Kutter, Juergen Phosphorus and Sulfur and the Related Elements, 1983 , vol. 15, p. 155 - 164

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被引用次数: 18

摘要

Abstract Bifunctional aminophosphanes (Et2N) 2P-[CH2] n,-P (NEt2) 2 (n= 1–10)(1) and Et2NP (R)-[CH2] nP (R) NEt2 (n= 2–4, R= Alkyl, Ph)(2), which are valuable intermediates in organophosphorus synthesis, are obtained by two methods. Because of the marked nucleophility of phosphorus in 1 and 2, reactions with Lewis acids take place very smoothly as is shown by preparation of (Et2N) 2P (X)-[CH2] 4-(X) P (NEt2) 2 (X= O, S, Se, Te, BH3, ...