Kinetic isotope effects for hydrogen abstraction from a series of cycloalkanes and branched alkanes by hydrogen atoms in the gaseous phase

N Fujisaki, A Ruf, T Gaeumann

文献索引：Fujisaki, Noboru; Ruf, Amanz; Gaeumann, Tino Journal of the American Chemical Society, 1985 , vol. 107, # 6 p. 1605 - 1610

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被引用次数: 18

摘要

Abstract: Hydrogen atoms produced in the radiolysis of water vapor were used to determine the kinetic isotope effects for the reactions He+ RH (RD)-+ H2 (HD)+ R.[kH (kD)], where RH is a perprotiated alkane and RD is the corresponding perdeuterated alkane. The alkanes studied include a homologous series of cycloalkanes, cyclopentane through cyclododecane, and isobutane, 2, 3-dimethylbutane, 2, 3, 4-trimethylpentane, and neopentane. The results ...