Catalyst??Free Suzuki??Type Coupling of Allylic Bromides with Arylboronic Acids

A Scrivanti, V Beghetto, M Bertoldini…

文献索引：Scrivanti, Alberto; Beghetto, Valentina; Bertoldini, Matteo; Matteoli, Ugo European Journal of Organic Chemistry, 2012 , # 2 p. 264 - 268

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被引用次数: 9

摘要

Abstract The coupling of arylboronic acids with electron-rich allylic bromides is accomplished in the absence of any transition-metal catalyst through conventional heating. The reaction is completely regioselective, affording only the α-coupled product, and can be carried out under mild aerobic conditions in an organic solvent; the presence of a base is required.