Journal of Sulfur Chemistry

A one-pot conversion of di-substituted thiourea to O-organyl arylthiocarbamate using FeCl3

SK Sahoo, S Chakraborty, BK Patel

文献索引：Sahoo, Santosh K.; Chakraborty, Supratim; Patel, Bhisma K. Journal of Sulfur Chemistry, 2012 , vol. 33, # 2 p. 143 - 153

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被引用次数: 1

摘要

Unsymmetrical thiourea, which on demand can generate isothiocyanate in the presence of FeCl3, can serve as a latent isothiocyanate functionality and circumvent the difficulties associated with the direct use of reactive isothiocyanate functionality. An unusual and unorthodox reactivity has been achieved during a one-pot reaction of an unsymmetrically di- substituted thiourea with an alcohol in the presence of FeCl3 leading to an expeditious ...