The Journal of Organic Chemistry

Rearrangement of organometallic compounds. 25. Carbon-skeletal [1, 2] anionic rearrangements and the. pi.-orbital overlap constraint: the question of nucleophilic …

JJ Eisch, CA Kovacs, P Chobe

文献索引：Eisch, John J.; Kovacs, Csaba A.; Chobe, Prabohd Journal of Organic Chemistry, 1989 , vol. 54, # 6 p. 1275 - 1284

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被引用次数: 16

摘要

Results Selection of Carbanion Substrates. In order to learn whether the n-overlap requirement would be a general constraint in skeletal rearrangement, we chose cyclic hydrocarbon, amine, and ether substrates, in which the starting carbanion would be constrained by the ring of which it was a member (encircled H in 11-16).