Chemistry Letters

AUTORECYCLING OXIDATION OF AMINES TO CARBONYL COMPOUNDS CATALYZED BY 3, 4-DISUBSTITUTED 4-DEAZATOXOFLAVIN DERIVATIVES

T Nagamatsu, Y Hashiguchi, Y Sakuma, F Yoneda

文献索引：Nagamatsu, Tomohisa; Hashiguchi, Yuko; Sakuma, Yoshiharu; Yoneda, Fumio Chemistry Letters, 1982 , p. 1309 - 1312

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被引用次数: 9

摘要

3, 4-Disubstituted 4-deazatoxoflavin derivatives (II) were prepared by the condensation of 6- (1-methylhydrazino) uracils (I) with appropriate α-diketones. The compounds II oxidized long- chain alkylamines such as n-octylamine and n-dodecylamine besides benzylamine and cyclohexylamine to yield the corresponding carbonyl compounds via imines, catalytically with a markedly high turnover number.