Syntheses, three types of hydrogen-bonded assembly structures, and magnetic properties of [Fe III (Him) 2 (hapen)] Y· solvent (Him= imidazole, hapen= N, N′-bis (2- …

…, K Murakami, T Fujinami, K Nishi, N Matsumoto…

文献索引：Koike, Masataka; Murakami, Keishiro; Fujinami, Takeshi; Nishi, Koshiro; Matsumoto, Naohide; Sunatsuki, Yukinari Inorganica Chimica Acta, 2013 , vol. 399, p. 185 - 192

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被引用次数: 9

摘要

Five iron (III) complexes of [FeIII (Him) 2 (hapen)] Y· solvent with five different counter anions were synthesized, where Him= imidazole, H2hapen= N, N′-bis (2- hydroxyacetophenylidene) ethylenediamine, Y= BPh4−(1), CF3SO3−(2), PF6−(3), ClO4−(4), and BF4−(5), and solvent= methanol or H2O. Each FeIII ion has octahedral coordination geometry with N2O2 donor atoms of the equatorial tetradentate ligand (hapen) and two ...