Journal of the American Chemical Society

Micellar systems as supercages for reactions of geminate radical pairs. Magnetic effects

NJ Turro, GC Weed

文献索引：Turro, Nicholas J.; Weed, Gregory C. Journal of the American Chemical Society, 1983 , vol. 105, # 7 p. 1861 - 1868

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被引用次数: 162

摘要

Abstract: The photochemistry of dibenzyl ketone (DBK) and other molecules capable of producing benzyl radicals and substituted benzyl radicals has been investigated in micellar systems. The cage effect (percent of unscavengeable radical pairs produced by photolysis) was measured under a variety of conditions, and the results are compared with those obtained in homogeneous organic solvents. For example, parameters such as mean ...