Oxidations catalyzed by osmium compounds. Part 1: Efficient alkane oxidation with peroxides catalyzed by an olefin carbonyl osmium (0) complex

GB Shul'pin, AR Kudinov, LS Shul'pina…

文献索引：Shul'pin, Georgiy B.; Kudinov, Aleksandr R.; Shul'pina, Lidia S.; Petrovskaya, Elena A. Journal of Organometallic Chemistry, 2006 , vol. 691, # 5 p. 837 - 845

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被引用次数: 41

摘要

A carbonyl osmium (0) complex with π-coordinated olefin,(2, 3-η-1, 4-diphenylbut-2-en-1, 4- dione) undecacarbonyl triangulotriosmium (1), efficiently catalyzes oxygenation of alkanes (cyclohexane, cyclooctane, n-heptane, isooctane, etc.) with hydrogen peroxide, as well as with tert-butyl hydroperoxide and meta-chloroperoxybenzoic acid in acetonitrile solution. Alkanes are oxidized to corresponding alcohols, ketones (aldehydes) and alkyl ...