Surface-mediated isomerization and oxidation of allyl alcohol on copper (110)

RL Brainard, CG Peterson…

文献索引：Brainard, Robert L.; Peterson, Cynthia G.; Madix, Robert J. Journal of the American Chemical Society, 1989 , vol. 111, # 13 p. 4553 - 4561

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被引用次数: 18

摘要

Abstract: Allyl alcohol reacts with clean and oxygen-covered Cu (110) surfaces to produce propanal, acrolein, n-propyl alcohol, and hydrogen under ultrahigh-vacuum conditions. Very small amounts of propylene and water are also formed. This pattern of reactivity contrasts sharply to the selective oxidation to acrolein observed on Ag (110). On the clean Cu (110) surface allyl alcohol undergoes 0-H cleavage to form the surface alkoxide CH2= CHCH20 ...