Enantioselective synthesis of epoxides via Sharpless epoxidation of alkenylsilanols

TH Chan, LM Chen, D Wang…

文献索引：Chan, T. H.; Chen, L. M.; Wang, D.; Li, L. H. Canadian Journal of Chemistry, 1993 , vol. 71, # 1 p. 60 - 67

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被引用次数: 35

摘要

AND D. WANG' AND L. H. LI Institute of Chernisrry, Acnclernia Sinicn, Beijing, People's Republic of Clzirzn TH CHAN, LM CHEN, D. WANG, and L. H. LI. Can. J. Chem. 71, 60 (1993). Enantioselective synthesis of simple epoxides can be achieved by Sharpless epoxidation of alkenylsilanols followed by protodesilylation of the chiral epoxysilanols. The approach has been applied to the synthesis of frontalin. ... T. H. CHAN, LM CHEN, D. WANG et LH Lr. Can. J. Chem. 71, 60 (1993). ...