Aryl Radical Formation by Copper (I) Photocatalyzed Reduction of Diaryliodonium Salts: NMR Evidence for a CuII/CuI Mechanism

A Baralle, L Fensterbank, JP Goddard…

文献索引：Baralle, Alexandre; Fensterbank, Louis; Goddard, Jean-Philippe; Ollivier, Cyril Chemistry - A European Journal, 2013 , vol. 19, # 33 p. 10809 - 10813

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被引用次数: 60

摘要

Hypervalent iodine chemistry is currently a field of intense development.[1] Thanks to the variety of possible derivatives, iodonium salts have proven to be useful and versatile reagents in organic synthesis.[2] Whereas most investigations focus on electrophilic arylation and alkenylation, homolytic reduction of iodonium salts has rarely been examined. Such transformations have typically been accomplished either by electrochemical or ...