Tetrahedron

The palladium-catalysed conjugate addition type reaction of arylmercury compounds with α, β-unsaturated ketones in a two-phase system

S Cacchi, D Misiti, G Palmieri

文献索引：Cacchi, S.; Misiti, D. Tetrahedron, 1981 , vol. 37, # 16 p. 2941 - 2946

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被引用次数: 28

摘要

Pd-catalysed reaction of arylmercury compounds with α, β-enones in an acidic two-phase system provides a mild and selective way to β-aryl ketones. The present conjugate addition type reaction may accommodate a wide variety of functional groups. Thus, aryl units containing electron-donating and electron-withdrawing substituents such as-Me,-Cl,-CHO,- COMe,-COOMe,-COOH,-OH,-OMe,-NHCOMe and-NO2 were successfully transferred to ...