The Journal of Organic Chemistry

Bis (methoxycarbonyl) sulfur diimide, a convenient reagent for the allylic amination of alkenes

G Kresze, H Münsterer

文献索引：Kresze, G; Muensterer, H. Journal of Organic Chemistry, 1983 , vol. 48, # 20 p. 3561 - 3564

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被引用次数: 53

摘要

Notes conditions. 2 As a rule, these ene products spontaneously undergo a [2, 3]- sigmatropic rearrangement to afford N-(2-alkeny1) diamino sulfanes 3 (Scheme I). Particularly remarkable is the pronounced selectivity of product formation in these cases, as documented by many examples. From the results of our investigations3 the following conclusions can be drawn.(i) Whenever possible, the C= C bond of the diaminosulfanes 3 ...