The substituent effect. 14. The solvolysis of 6-and 7-substituted 1-(2-naphthyl) ethyl chlorides.

Y Tsuno, M Sawada, T Fujii, Y Yukawa

文献索引：Tsuno,Y. et al. Bulletin of the Chemical Society of Japan, 1979 , vol. 52, p. 3033 - 3042

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被引用次数: 30

摘要

Nine of the title compounds were synthesized, and their solvolysis rates were determined in 80%(v/v) aq acetone at 45° C. The effects of the pi-donor substituents for each substituent position are shown to be excellently described in terms of inductive (I) and pi-electronic (Pi) effects by means of the LSFE equation (logk⁄ k 0= ρ i σ i+ ρ π+ σ π+), Just as with those in the 1-naphthyl systems. When those data are joined with all our substituent effects data for the ...