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Studies of nitrile oxide cycloadditions, and the phenolic oxidative coupling of vanillin aldoxime by Geobacillus sp. DDS012 from Italian rye grass silage

DR Kelly, SC Baker, DS King, DS de Silva…

文献索引:Kelly, David R.; Baker, Simon C.; King, David S.; Silva, Deepa S. de; Lord, Gwyn; Taylor, Jason P. Organic and Biomolecular Chemistry, 2008 , vol. 6, # 6 p. 787 - 796

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被引用次数: 21

摘要

During studies directed towards the discovery of nitrile hydrolysing enzymes from thermophiles, vanillin aldoxime was incubated with the thermophilic organism, Geobacillus sp. DDS012 isolated from Italian rye grass (Lolium multiflorum) silage. The predominant product was a dihydro-dimer, which could only be characterised by LC-MS. This was initially imagined to be the product of cycloaddition of vanillin aldoxime with the corresponding ...