Tetrahedron

A highly efficient kinetic resolution of γ-and β-trimethylsilyl secondary allylic alcohols by the sharpless asymmetric epoxidation

Y Kitano, T Matsumoto, F Sato

文献索引：Kitano, Yasunori; Matsumoto, Takashi; Sato, Fumie Tetrahedron, 1988 , vol. 44, # 13 p. 4073 - 4086

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被引用次数: 83

摘要

Kinetic resolution of γ-and β-trimethylsilyl secondary allylic alcohols proceeds with very large and synthetically satisfactory rate differences for the two enantiomers, respectively, thus providing a convenient and widely applicable method for preparation of various kinds of homochiral compounds.