Dalton Transactions

A mixed ligand route for the construction of tetrahedrally coordinated porous lithium frameworks

X Zhao, T Wu, X Bu, P Feng

文献索引：Zhao, Xiang; Wu, Tao; Bu, Xianhui; Feng, Pingyun Dalton Transactions, 2011 , vol. 40, # 32 p. 8072 - 8074

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被引用次数: 12

摘要

Reported here are two 4-connected 3D frameworks based on monomeric lithium nodes, which are synthesized through a mixed ligand route. By combining a negatively charged imidazole ligand and a neutral bis (imidazolyl) methane ligand (or one of its derivatives), neutral frameworks adopting chiral quartz-dual and diamond topologies have been obtained. These materials have low framework density and can reversibly adsorb ...