A novel magnetic nano-CoFe2O4 supported Sb ([CoFe2O4@ SiO2–DABCO–Sb]) was successfully constructed, which exhibited high catalytic activity for one-pot three-component synthesis of multisubstituted pyrroles in the reaction of amines, nitroolefin and 1, 3- dicarbonyl compounds. The magnetic heterogeneous catalyst could be easily recovered using an external magnet and reused many times without significant loss of catalytic ...