前往化源商城

A Comparative Study of Cyclometallated Palladium (II) Compounds with Terdentate [C, N, S] Pincer Ligands− Crystal and Molecular Structure of [Pd {4??MeC6H3C (Me …

…, J Martínez, T Pereira, M López??Torres…

文献索引:Amoedo, Adriana; Grana, Maria; Martinez, Javier; Pereira, Teresa; Lopez-Torres, Margarita; Fernandez, Alberto; Fernandez, Jesus J.; Vila, Jose M. European Journal of Inorganic Chemistry, 2002 , # 3 p. 613 - 620

全文:HTML全文

被引用次数: 37

摘要

Abstract Treatment of the thiosemicarbazone ligands 4-MeC 6 H 4 C (Me)= NN (H) C (= S) NHMe (a), 4-MeC 6 H 4 C (Me)= NN (H) C (= S) NHEt (b), and 4-MeC 6 H 4 C (Me)= NN (H) C (= S) NHPh (c) with K 2 [PdCl 4] produced the tetranuclear palladium (II) compounds [Pd {4-MeC 6 H 3 C (Me)= NNC (= S) NHMe}] 4 (1a),[Pd {4-MeC 6 H 3 C (Me)= NNC (= S) NHEt}] 4 (1b), and [Pd {4-MeC 6 H 3 C (Me)= NNC (= S) NHPh}] 4 (1c) with deprotonation ...