Raney Ni–Al alloy in a dilute aqueous alkaline solution has been shown to be a powerful reducing agent and is highly effective for the reduction of alkylbenzils and alkoxybenzils to afford the corresponding 1, 2-diarylethers at 90° C, in the absence of organic solvents. 4, 4'- Dinitrobenzil was transformed selectively to 1, 2-bis (4-aminophenyl)-ethane.