Journal of Chemical Research

Correlation of the specific rates of solvolysis of trimethylsilylmethyl trifluoromethanesulfonate using a two-term Grunwald-Winstein equation

DN Kevill, EG Goken, BC Park

文献索引：Kevill, Dennis N.; Goken, Erin G.; Park, Byoung-Chun Journal of Chemical Research, 2006 , # 3 p. 173 - 175

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被引用次数: 1

摘要

The specific rates of solvolysis of trimethylsilylmethyl trifluoromethanesulfonate have been measured at 25.0° C in ethanol, methanol, and 2, 2, 2-trifluoroethanol (TFE) and their mixtures with water. Determinations were also made in aqueous acetone and in TFE- ethanol mixtures. An extended (two-term) Grunwald-Winstein equation correlation gave sensitivities towards changes in solvent nucleophilicity and solvent ionising power as ...