Gas??phase thermolysis of tert??butyl hydroperoxide with benzene and chlorobenzene in the temperature range 200??300° C

P Mulder, R Louw

文献索引：Mulder, Peter; Louw, Robert Recueil: Journal of the Royal Netherlands Chemical Society, 1984 , vol. 103, # 10 p. 282 - 287

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摘要

Abstract Thermolysis of tert-butyl hydroperoxide (1) in nitrogen with an excess of benzene in the temperature range 200-300 C, leads to biphenyl (2) as the only observable benzene- derived product. With chlorobenzene, dichlorobiphenyls (4) are formed, together with chlorobiphenyl (5), ca. 12% on 4, and phenol (20-25% on 4); chlorophenols are not produced. The use of ca. equimolar quantities of iodine based on 1 results in formation of ...