Generation and investigation of various (alkylamino) phenylsilyllithium species–behaviour in coupling reactions with chlorosilanes

K Trommer, U Herzog, U Georgi…

文献索引：Trommer, K.; Herzog, U.; Georgi, U.; Roewer, G. Journal fuer Praktische Chemie/Chemiker-Zeitung, 1998 , vol. 340, # 6 p. 557 - 561

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被引用次数: 12

摘要

Abstract The partially diethylamino substituted phenyl-chloromono-and-disilanes Cl 2 Ph (NEt 2) Si (2) Cl 2 Ph (NEt 2) 2 Si (3),[ClPh (NEt 2) Si-] 2 (7) and Cl (NEt 2) PhSi [BOND] SiPh (NEt 2) 2 (8) were synthesized. 3 and 8 are able to react with lithium powder to form the corresponding silyllithium compounds. The resulting species were characterized in solution by 13 C and 29 Si NMR spectroscopy. To prove the expected substitution patterns of the ...