Journal of the American Chemical Society

Selective Reactions of the Silicon-Hydrogen Group with Grignard Reagents. The Preparation of Some Unsymmetrical Silane Derivatives

H Gilman, EA Zuech

文献索引：Gilman; Zuech Journal of the American Chemical Society, 1959 , vol. 81, p. 5925,5927

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被引用次数: 20

摘要

Grignard reagents react readily with phenyl-and diphenylsilane in THF to give good yields of the corresponding di-and trisubstituted silanes. Triphenylsilane was found to react with some Grignard reagents, but only after extended refluxing. Utilizing proper conditions, it was possible to join selectively the silicon-hydrogen groups of phenylsilane to synthesize a number of unsymmetrical organosilicon derivatives containing three or four unlike ...