Probing the structure, conformation, and stereochemical exchange in a family of lanthanide complexes derived from tetrapyridyl-appended cyclen

…, SL Heath, AM Kenwright, I Kuprov, S Faulkner

文献索引：Natrajan, Louise S.; Khoabane, Ntai M.; Dadds, Benjamin L.; Muryn, Christopher A.; Pritchard, Robin G.; Heath, Sarah L.; Kenwright, Alan M.; Kuprov, Ilya; Faulkner, Stephen Inorganic Chemistry, 2010 , vol. 49, # 17 p. 7700 - 7709

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被引用次数: 30

摘要

NMR and luminescence spectroscopy have been used in combination with calculations and crystallographic data to probe the solution speciation of lanthanide complexes of a cyclen derivative bearing four picolyl pendent arms and to study the interchange pathways between diastereoisomers.