Effects of Structural Factors in Silyl Ethers Derived from Terminal Acetylenic Alcohols on 1, 4-O→ Csp Migration of the Silyl Group

AS Medvedeva, VV Novokshonov, AV Mareev…

文献索引：Medvedeva; Novokshonov; Mareev; Borisova Russian Journal of Organic Chemistry, 2003 , vol. 39, # 3 p. 336 - 339

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被引用次数: 3

摘要

Abstract Effects of structural factors in silyl ethers derived from terminal acetylenic alcohols on 1, 4-O→ C sp migration of the silyl group in the Iotsitch reagent were studied. The effect of steric factor at the carbon atom neighboring to the reaction center was found to be stronger than that at the silicon atom in the migrating group.