Environmental science & technology

Tropospheric reaction products and mechanisms of the Hydrochlorofluorocarbons 141b, 142b, 225ca, and 225cb

EC Tuazon, R Atkinson

文献索引：Tuazon, Ernesto C.; Atkinson, Roger Environmental Science & Technology, 1994 , vol. 28, # 13 p. 2306 - 2313

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被引用次数: 13

摘要

Fhe C1 atom-initiated photooxidation of CF3CF2CHC12 HCFC-225ca) produced CF3CF2C (O) Cl in 100% yield, shile CFzClCFzCHFCl (HCFC-225cb) yielded CF2ClCF2-? O) F (99%) and C (O) FCl (l%). The two-carbon aldeiydes CFClzCHO and CFzClCHO were positively observed is photooxidation products of CFC12CH3 (HCFC-14lb) ind CF2ClCH3 (HCFC- l42b), respectively. Their calcuated 100% formation yields show conclusively that under ...