Electrochemical synthesis of euglobal-G1,-G2,-G3,-G4,-T1 and-IIc

K Chiba, T Arakawa, M Tada

文献索引：Chiba, Kazuhiro; Arakawa, Takaaki; Tada, Masahiro Journal of the Chemical Society - Perkin Transactions 1, 1998 , # 17 p. 2939 - 2942

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被引用次数: 31

摘要

Six natural euglobals were synthesized by electrochemical methods. In a key step, cycloaddition between in situ generated quinomethanes and terpenes was performed on the surface of PTFE-fibre coated electrode to give natural products using 2, 3-dichloro-5, 6- dicyano-p-hydroquinone (DDQH2) as a redox mediator. In this reaction system, biomimetic generation and cycloaddition of the unstable quinomethanes were efficiently completed ...