Organic mass spectrometry

Cyclic ions in the mass spectra of trimethylsilyl derivatives of substituted o??dihydroxybenzenes

RJ Horvat, SD Senter

文献索引：Horvat, Robert J.; Senter, Samuel D. Organic Mass Spectrometry, 1983 , vol. 18, # 10 p. 413 - 417

全文：HTML全文

被引用次数: 5

摘要

Abstract The mass spectra of trimethylsilyl (TMS) ethers/methyl esters of phenolic acids containing o-dihydroxybenzene groups have base peaks at [M− 119]+ instead of the usual [M− 15]+ and [M− 31]+ that are characteristic of TMS/methyl esters of monohydroxyphenolic acids. These ions, formed by the loss of 31+ 88 u from the parent ion, possess a cyclic moiety as proven by substitution of deuterium atoms for hydrogen atoms in the TMS ...